DaKS - University of Kassel's research data repository
DaKS is the institutional repository of the University of Kassel for research data. It offers structured storage of research data alongside with descriptive metadata, long-term archiving for at least 10 years and – if requested – the publication of the dataset with a DOI.
DaKS is managed by the university library and the IT Service Centre of the University of Kassel. It is hosted at Philipps-Universität Marburg. We are happy to advise you via daks@uni-kassel.de.
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This study investigates the thermo- and photo-oxidative degradation behavior of a bio-based polyamide (PA) 5.10, both neat and 20 wt.% regenerated cellulose fiber-reinforced (RCF). In addition, these materials were modified with two different UV stabilizers, AddWorks IBC760 (IBC), a hindered amine light stabilizer, and LUBIO UV16 (LUBIO), an UV absorber. 168 hours of storage at temperatures of 23 °C, 50 °C, 70 °C to 90 °C at 50 %rH, with and without UV exposure of 1000 W/m², revealed significant degradation effects both in neat and LUBIO-stabilized batches, including molecular chain splitting processes, embrittlement, reduction in surface polarity and pronounced yellowing. In contrast, the IBC provided superior stabilization, maintaining thermal and mechanical properties as well as color stability. RCF-reinforced PA 5.10 exhibited moisture-induced plasticization, increasing ductility as well as aging-induced embrittlement at elevated temperatures. SEM imaging confirmed an increased share of fiber ruptures in the UV exposed neat RCF-composites, while IBC-stabilized specimens preserved the high amount of fiber pull-outs. Melt volume rate measurements demonstrate the reduction in molecular weight due to the thermo- and photo-oxidative degradation. A linear polynomial regression was also used to demonstrate the characteristic degradation mechanisms of polyamide. Overall, the IBC-stabilized batches show a significant stabilization effect across all tested storage conditions. These findings highlight the potential of UV-stabilized RCF-reinforced PA 5.10 composites as sustainable replacements for petro-based polyamide composites in applications requiring long-term resistance to thermo- and photo-oxidative stress.
This data set consists of the measured data from the conducted experiments as well as the data analysis.
In case you use the data please cite the corresponding article. The corresponding publication is currently in publication process.